Product ID:SPECIALLY DENATURED ALCOHOL 3A, 200 PROOF
MSDS Date:11/01/1998
FSC:6810
NIIN:00-201-0906
MSDS Number: BDJHM

AAPER ALCOHOL & CHEMICAL CO.

11 ISAAC SHELBY DR.
SHELBYVILLE, KY 40066-0339
US

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 502-633-0650

Cage: 61305

AAPER ALCOHOL AND CHEMICAL CO

339 SHELBYVILLE, KY 40066-0339 US

Telephone: 502-633-0650

Cage: 61305

ETHYL ALCOHOL (ETHANOL)

CAS: 64-17-5

RTECS: KQ6300000

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM; 9192

METHYL ALCOHOL (METHANOL) (SARA III)

CAS: 67-56-1

RTECS: PC1400000

OSHA PEL S,200PPM/250STEL

ACGIH TLV: S,200PPM/250STEL; 93

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE CONTACT: LIQUID OR VAPOR MAY CAUSE
IRRITATION. SKIN CONTACT: MAY CAUSE IRRITATION AND DEFATING OF
SKIN ON PROLONGED CONTACT.
Effects of Overexposure:INHALATION: EXPOSURE TO OVER 1000 PPM MAY CAUSE
IRRITATION OF THE THROAT, HEADACHE, DROWSINESS AND LASSITUDE, LOSS
OF APPETITE, AND INABILITY TO CONCENTRATE. INGESTION: CAN CAUSE
DEPRESSION OF CENTRAL NERVOUS SYSTEM, NAUSEA, DIARRHEA, VOMITING.

First Aid:ISWALLOWING: IF VICTIM IS CONSCIOUS, HAVE VICTIM DRINK WATER
OR MILK TO DILUTE. NEVER GIVE ANYTHING BY MOUTH IF VICTIM IS
UNCONSCIOUS OR HAVING CONVULSIONS. CALL A PHYSICIAN OR CHEMTREC
(POISON CONTRO L) IMMEDIATELY. INDUCE VOMITING ONLY IF ADVISED BY
PHYSICIAN. INHALATION: IMMEDIATELY REMOVE VICTIM TO FRESH AIR. IF
VICTIM HAS STOPPED BREATHING, GIVE ARTIFICIAL RESPIRATION,
PREFERRABLY MOUTH-TO-MOU TH. GET MEDICAL ATTENTION IMMEDIATELY.
CONTACT WITH EYE OR SKIN: IMMEDIATELY FLUSH AFFECTED AREA WITH
PLENTY OF COOL WATER FOR AT LEAST 15 MINUTES. REMOVE AND WASH
CONTAMINATED CLOTHING BEFORE REUSE. GET MEDICAL ATTENTION
IMMEDIATELY.

Flash Point Method:TCC
Flash Point:=12.8C, 55.F
Autoignition Temp:=362.8C, 685.F
Lower Limits:3.3
Upper Limits:19.0
Extinguishing Media:USE DRY CHEMICAL, "ALCOHOL" FOAM OR CARBON DIOXIDE.
WATER MAY BE INEFFECTIVE BUT SHOULD BE USED TO KEEP FIRE-EXPOSED
CONTAINERS COOL..
Fire Fighting Procedures:IF LEAK OR SPILL HAS NOT IGNITED, USE WATER
SPRAY TO DISPERSE VAPORS AND PROTECT MEN ATTEMPTING TO STOP LEAK.
WATER MAY BE USED TO FLUSH SPRILLS AWAY FROM EXPOSURES AND TO
DILUTE SPILLS TO NONFLAMMABL E MIXTURES.
Unusual Fire/Explosion Hazard:FIREFIGHTERS SHOULD WEAR SELF-CONTAINED
BREATHING APPARATUS IN THE POSITIVE PRESSURE MODE WITH A FULL FACE
PIECE WHEN THERE IS A POSSIBILITY OF EXPOSURE TO SMOKE, FUMES, OR
HAZARDOUS DECOMPOSITION PRO DUCTS.

Spill Release Procedures:WEAR APPROPRIATE RESPIRATORY PROTECTION AND
PROTECTIVE CLOTHING. CONTAIN SPILLED MATERIAL.TRANSFER TO SECURE
CONTAINERS. WHERE NECESSARY, COLLECT USING ABSORBENT MEDIA. IN THE
EVENT OF AN UNCONTROALLE D RELEASE, THE USER SHOULD DETERMINE IF
RELEASE IS REPORTABLE UNDER APPLICABLE LAWS AND REGULATIONS.
Neutralizing Agent:NONE

Handling and Storage Precautions:PROTECT CONTAINER AGAINST PHYSICAL
DAMAGE. DETACHED OR OUTSIDE STORAGE PREFERRED. INSIDE STORAGE IN
NFPA APPROVED FALMMABLE LIQUID STORAGE ROOM OR CABINET. ELIMINATE
ALL IGNITION SOURCES. NFPA 30 SHOU LD BE FOLLOWED FOR STORAGE AND
HANDLING. ISOLATE FROM OXIDIZERS, IGNITION SOURCES AND
EXPLOSIVES.
Other Precautions:BOND AND GROUND CONTAINERS WHEN TRANSFERRING LIQUID.
NEVER USE PRESSURE TO EMPTY. REPLACE CLOSURE SECURELY AFTER EACH
USE. OBSERVE ALL HAZARD PRECAUTIONS FOR EMPTIED CONTAINERS. EMPTY
CONTAINERS RETAI N PRODUCT RESIDUE, OBSERVE ALL PRECAUTIONS GIVEN
IN MSDS. NOT FOR HOUSEHOLD USE.

Respiratory Protection:WHERE EXPOSURE IS LIKELY TO EXCEED ACCEPTABLE
CRITERIA, USE NIOSH/MSHA APPROVED RESPIRATORY PROTECTION EQUIPMENT.
RESPIRATORS SHOULD BE SELECTED BASED ON THE FORM AND CONCENTRATION
OF CONTAMINANT IN A IR AND IN ACCORDANCE WITH OSHA (29 CFR
1910.134).
Ventilation:HANDLE IN THE PRESENCE OF ADEQUATE VENTILATION.
Protective Gloves:IMPERVIOUS.
Eye Protection:WEAR SAFETY GLASSES MMETING THE SPECIFICATION OF ANSI
STANDARD Z87.1.
Other Protective Equipment:WEAR PROTECTIVE CLOTHING WHICH IS IMPERVIOUS
TO THE PRODUCT FOOR THE DURATION OF THE ANTICIPATED EXPOSURE IF
THERE IS POTENTIAL FOR PROLONGED OR REPEATED CONTACT.
Work Hygienic Practices:DO NOT EAT, DRINK OR SMOKE WHILE WORKING WITH
THIS PRODUCT.
Supplemental Safety and Health
EYE: CHEMICAL SAFETY GOOGLES MEETING THE SPECIFICATIONS OF ANSI
STANDARD Z87.1 SHOULD BE WORN WHENEVER THERE IS THE POSSIBILITY OF
SPLASHING OR OTHER CONTACT WITH THE EYES. FOR INDUSTRIAL USE ONLY.
CO NTAINS METHANOL: INTAKE CAN CAUSE BLINDNESS!

HCC:F5
Boiling Pt:=78.3C, 172.9F
Vapor Pres:44.6 MMHG
Vapor Density:1.59
Spec Gravity:0.793
Evaporation Rate & Reference:5.9 (BUTYL ACETATE=1)
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR, COLORLESS LIQUID, MILD ALCOHOLIC ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
CONTACT WITH ACETYL CHLORIDE AND A WIDE RANGE OF OXIDIZING AGENTS MAY
REACT VIOLENTLY.
Stability Condition to Avoid:KEEP AWAY FROM HEAT OR IGNITION SOURCE

Waste Disposal Methods:ALL RECOVERED MATERIAL SHOULD BE PACKAGED,
LABLELED, TRANSPORTED, AND DISPOSED OF, OR RECLAIMED IN CONFORMANCE
WITH APPLICABLE LAWS AND REGULATIONS IN CONFORMANCE WITH GOOD
ENGINEERING PRACTICES.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Transport Information:DEPARTMENT OF TRANSPORTATION (DOT): DOT
CLASSIFICATION: 3 (FLAMMABLE LIQUID). DOT PROPER SHIPPING NAME:
ETHANOL SOLUTION. OTHER DOT INFORMATION: IDENTIFICATION NUMBER UN
1170, PG II. EMERGENCY RESPON SE GUIDE NO. 26. ATF DISTILLED
SPIRITS ACT: USE OF ETHYL ALCOHOL WITHOUT PRIOR PAYMENT OF
APPLICABLE EXCISE TAX IS STRICTLY CONTROLLED BY REGULATIONS
PROMULGATED & ENFORCED BY THE BUREAU OF ALCOHOL, T OBACCO, AND
FIREARMS (ATF), DEPARTMENT OF THE TREASURY. GOVERNING REGULATIONS
HAVE BEEN DEFINED IN TITLE 27, CODE OF FEDERAL REGULATIONS.

SARA Title III Information:SECTION 313: METHANOL, 67-56-1, 4.78%.
Federal Regulatory Information:TOXIC SUBSTANCE CONTROL ACT (TSCA): THIS
PRODUCT IS LISTED IN THE TOXIC SUBSTANCE CONTROL ACT (TSCA)
INVENTORY OF CHEMICAL SUBSTANCES.